Search results for "heaviest elements"

showing 4 items of 4 documents

TASCAを用いたCn, Nh, Fl化学実験のためのHg, Tl, PbのSiO2及びAu表面に対するオンライン化学吸着研究

2018

Online gas-solid adsorption studies with single atom quantities of Hg, Tl, and Pb on SiO$_{2}$ and Au surfaces were carried out using short-lived radioisotopes with half-lives in the range of 4-49 s. This is a model study to measure adsorption enthalpies of superheavy elements Cn, Nh, and Fl. The short-lived isotopes were produced and separated by the gas-filled recoil separator TASCA at GSI. The products were stopped in He gas, and flushed into gas chromatography columns made of Si detectors whose surfaces were covered by SiO$_{2}$ or Au. The short-lived Tl and Pb were successfully measured by the Si detectors with the SiO$_{2}$ surface at room temperature. On the other hand, the Hg did no…

Analytical chemistrychemistry.chemical_elementElectronic structure010402 general chemistry01 natural sciencesadsorption studiethermochromatographyHomologs of superheavy elementRELATIVISTIC PERIODIC DFTMetalGSIAdsorptionCHEMISTRY0103 physical sciencesisothermal chromatographyPhysical and Theoretical ChemistrySUPERHEAVY ELEMENTS010306 general physicsCoperniciumChemistryQUARTZ SURFACE0104 chemical sciencesgas phase chromatography of single atomHEAVIEST ELEMENTSFleroviumELECTRONIC-STRUCTUREvisual_artYield (chemistry)METALvisual_art.visual_art_mediumGas chromatographyRelativistic quantum chemistryphysical preseparationSYSTEMRadiochimica acta
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Precision Measurement of the First Ionization Potential of Nobelium

2018

One of the most important atomic properties governing an element's chemical behavior is the energy required to remove its least-bound electron, referred to as the first ionization potential. For the heaviest elements, this fundamental quantity is strongly influenced by relativistic effects which lead to unique chemical properties. Laser spectroscopy on an atom-at-a-time scale was developed and applied to probe the optical spectrum of neutral nobelium near the ionization threshold. The first ionization potential of nobelium is determined here with a very high precision from the convergence of measured Rydberg series to be 6.626 21±0.000 05  eV. This work provides a stringent benchmark for st…

ENERGIESGeneral Physics and Astronomychemistry.chemical_elementElectron[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]01 natural sciences7. Clean energysymbols.namesakeIonizationEQUAL-TO 1040103 physical sciencesLAWRENCIUMBUFFER GASPhysics::Atomic PhysicsSUPERHEAVY ELEMENTSLASER SPECTROSCOPY010306 general physicsSpectroscopyPhysicsNEUTRAL YTTERBIUM010308 nuclear & particles physicsHEAVIEST ELEMENTSchemistryRydberg formulasymbolsEXCITED-LEVELSNobeliumACTINIDESIonization energyAtomic physicsRelativistic quantum chemistryLawrencium
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The performance of the cryogenic buffer-gas stopping cell of SHIPTRAP

2018

Direct high-precision mass spectrometry of the heaviest elements with SHIPTRAP, at GSI in Darmstadt, Germany, requires high efficiency to deal with the low production rates of such exotic nuclides. A second-generation gas stopping cell, operating at cryogenic temperatures, was developed and recently integrated into the relocated system to boost the overall efficiency. Offline measurements using 223Ra and 225Ac recoil-ion sources placed inside the gas volume were performed to characterize the gas stopping cell with respect to purity and extraction efficiency. In addition, a first online test using the fusion-evaporation residue 254No was performed, resulting in a combined stopping and extrac…

Speichertechnik - Abteilung BlaumNuclear and High Energy PhysicsMaterials scienceDIRECT MASS MEASUREMENTSProtonBuffer gaschemistry.chemical_elementPenning trapsMass spectrometry7. Clean energy01 natural sciencesFusion-evaporation reaction productsNuclear physicsIonization0103 physical sciencesCalibrationStopping and extraction efficiencyNuclide010306 general physicsInstrumentationCALIBRATION[PHYS]Physics [physics]nobeliumSPECTROSCOPYMass spectrometry010308 nuclear & particles physicsTransfermium elementsCryogenic gas stopping cellExtraction timeHEAVIEST ELEMENTSchemistryIONIZATIONNobeliumOrder of magnitude
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Ca-48+Bk-249 Fusion Reaction Leading to Element Z=117: Long-Lived alpha-Decaying (270)Db and Discovery of Lr-266

2014

The superheavy element with atomic number Z=117 was produced as an evaporation residue in the 48Ca+249Bk fusion reaction at the gas-filled recoil separator TASCA at GSI Darmstadt, Germany. The radioactive decay of evaporation residues and their α-decay products was studied using a detection setup that allowed measuring decays of single atomic nuclei with half-lives between sub-μs and a few days. Two decay chains comprising seven α decays and a spontaneous fission each were identified and are assigned to the isotope 294117 and its decay products. A hitherto unknown α-decay branch in 270Db (Z=105) was observed, which populated the new isotope 266Lr (Z=103). The identification of the long-live…

superheavy nucleiseparatorgsitascaca-48-inducted reactionsheaviest elements
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